Upper Division Thermo
The Second Law of Thermodynamics is complicated and has many facets that are useful beyond the study of thermodynamics, including predicting the ultimate collapse of the universe and its beginning with a state of zero entropy. Whereas the First Law shows us how to "quantify" energy, the Second Law directs us to consider the "quality" of the energy in terms of what is defined as a "rational efficiency" when analyzing thermal systems.
For example, the First Law allows the design of a perpetual motion machine, while the Second Law prohibits its construction because every machine has losses, such as friction, that cannot be recovered.
Stated another way, the Second Law quantifies the ability of a thermodynamic system to perform work, and that ability to do work is directly related to the system operating temperatures. Higher temperatures mean higher system efficiency — higher steam temperatures increase efficiency in a steam plant, as do higher turbine inlet temperatures in a combustion turbine. Very low temperatures have a very limited ability to do useful work because the quality of the energy has been diluted.
Electricity is the most valuable form of energy available to us because it can be transmitted long distances, has a multitude of uses, and has a high energy density. Low-grade thermal energy has few uses, is not easily transported because of its very low energy density, and cannot be economically stored. The Second Law concludes that the thermodynamic value of thermal energy will always be less than that of electricity. Look back to your automobile for another analogy. The engine’s jacket water can efficiently provide the low-grade thermal energy to heat the occupants but is useless to provide the horsepower needed to move the vehicle forward.
This aspect of energy "quality" is missing when the First Law is used to calculate the "efficiency" of a CHP system. An example: Which would you rather have: A million Btu-equivalents of electricity available at your wall outlet or a million Btu of tepid bathwater? The First Law (quantity of energy) tells us they are equivalent and that you should be happy with either form of energy. The Second Law (quality of energy) says the value of the electricity is higher because of its superior ability to do useful work.
Comments (2)
http://gearturbine.260mb.com/
YouTube Video; Atypical New * GEARTURBINE / Retrodynamic
http://www.youtube.com/watch?v=0cPo9Lf44TE
GEARTURBINE -Atypical Combustion Turbine Engine, -State of the Art, -New Thermodynamic Technology, -With Retrodynamic "Dextrogiro vs Levogiro" Effect, is when the inflow direction moves is against of the circular rotary dynamic, RPM Rotor Move VS Inflow Conduits Way, making in a simple way a very strong concept of power thrust, a unique technical cuality. -Non Waste, parasitic losses form-function engine system for; cooling, lubrication & combustion; -Lubrication & Combustion inside a conduit radial position, out way direction, activated by centrifugal force (centrpetal to in), -Cooling in & out; In by Thermomix flow & Out by air Thermo transference, activated by the dynamic rotary move, -Increase the first compresion by going of reduction of one big circunference fan blades going to, -2two very long distance cautive compression inflow propulsion conduits (like a digestive system) (long interaction) in perfect equilibrium well balanced start were end like a snake bite his own tale, -Inside active rotor with 4 pairs of retrodynamic turbos (complete regeneration power system), -Mechanical direct "Planetary Gear" power thrust like a Ying Yang (very strong torque) (friendly loose friction) 2two small gears in polar position inside a bigger shell gear, wide out the rotor circunference were have much more lever power thrust, lower RPM in a simple way solution for turbines, to make posible for a some new work aplication (land). -3 Stages of inflow turbo compression before the combustion. -3 points united of power thrust; 1- Rocket Flames, 2-Planetary Gear & 3-Exhaust Propulson, all in one system. -Combustion 2two continue circular moving inside rocket Flames, like two dragons trying to bite the tail of the opposite other. -Hybrid flow system diferent kind of aerolasticity thermoplastic inflow propulsion types; single, action & reaction turbines applied in one same system, -Military benefits, No blade erosion by sand & very low heat target profile. -Power thrust by barr (tube); air sea land & generation aplication, -With the unique retrodynamic technical cuality of "dextrogiro vs levogiro" effect is when the inside flow moves against of the rotor moves making a very strong concept, RPM Rotor Move VS Inflow Conduits Way (an a example is like to move the head to the side of the strike ponch) -A pretender of very high % efficient power plant looking to make posible a cheap electrolysis. -Patent; Dic 1991 IMPI Mexico #197187